Publications

(Preprint) Wang, Z.; Bae, S.; Baljozović, M.; Adams, P.; Yong, D.; Service, E.; Moehl, T.; Niu, W.*; Tilley, S. D.* One-step Hydrothermal Synthesis of Sn-doped Sb2 Se3  for Solar Hydrogen Production ChemRxiv, 2024.
doi: 10.26434/chemrxiv-2024-rf0kh

(Preprint) Bae, S.; Moehl, T.; Service, E.; Kim, M.; Adams, P.; Wang, Z.; Choi, Y.; Ryu, J.*; Tilley, S. D.* Hole-Selective Hybrid TiO2 Layer towards Long-Term Stability of Low-Cost Photoanodes in Solar Water Oxidation ChemRxiv, 2024.
doi: 10.26434/chemrxiv-2024-n216n

(74) Bühler, J.; Muntwyler, A.; Roithmeyer, H.; Adams, P.; Besmer, M. L.; Blacque, O.; Tilley, S. D.* Immobilised Ruthenium Complexes for the Electrooxidation of 5-Hydroxymethylfurfural Chemistry A European Journal, 2024, e202304181.
doi: 10.1002/chem.202304181

TOC

(73) Roithmeyer, H.; Sévery, L.; Moehl, T.; Spingler, B.; Blacque, O.; Fox, T.; Ianuzzi, M.; Tilley, S. D.* Electrocatalytic Ammonia Oxidation with a Tailored Molecular Catalyst Heterogenized via Surface Host–Guest Complexation Journal of the American Chemical Society, 2024, 146, 430–436.
doi: 10.1021/jacs.3c09725

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(72) Adams, P.; Schnyder, R.; Moehl, T.; Bühler, J.; Labordet Alvarez, A.; Dimitrievska, M.; McKenna, K.; Yang, W.*; Tilley, S. D.* Post-Synthetic Silver Ion and Sulfurization Treatment for Enhanced Performance in Sb2Se3 Water Splitting Photocathodes Advanced Functional Materials, 2023, 2310596.
doi: 10.1002/adfm.202310596

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(71Tilley, S. D.* Will Cuprous Oxide Really Make It in Water-Splitting Applications? ACS Energy Letters, 2023, 8, 2338-2344.
doi: 10.1021/acsenergylett.3c00578

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(70) Park, J.; Shalvey, T. P.; Moehl, T.; Woo, K.; Major, J. D.; K.; Tilley, S. D.; K.; Yang, W.* Impedance spectroscopy of Sb2Se3 photovoltaics consisting of (Sb4Se6)n nanoribbons under light illumination Nanoscale, 2023, 15, 19757-19766.
doi: 10.1039/D3NR04082H

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(69) Tan, J.; Zhang, X.; Suh, J.; Ha, N.; Lee, J.; Tilley, S. D.*; Yang, W.* Molecular ink-derived chalcogenide thin films: Solution-phase mechanisms and solar energy conversion applications Materials Today Energy, 2023, 23, 101288.
doi: 10.1016/j.mtener.2023.101288

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(68) Adams, P.; Creazzo, F.; Moehl, T.; Crockett, R.; Zeng, P.; Novotny, Z.; Luber, S.*; Yang, W.*; Tilley, S. D.* Solution phase treatments of Sb2Se3 heterojunction photocathodes for improved water splitting performance Journal of Materials Chemistry A, 2023, 11, 8277-8284.
doi: 10.1039/D3TA00554B

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(67) Zhang, X.; Pollitt, S.; Jung, G.; Niu, W.; Adams, P.; Bühler, J.; Grundmann, N. S.; Erni, R.; Nachtegaal, M.; Ha, N.; Jung, J.; Shin, B.; Yang, W.*; Tilley, S. D.* Solution-Processed Cu2S Nanostructures for Solar Hydrogen Production Chemistry of Materials, 2023, 35, 2371-2380.
doi: 10.1021/acs.chemmater.2c03489

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(66Tilley, S. D.* Metal-like molecules Nature Catalysis, 2022, 5, 359-360.
doi: 10.1038/s41929-022-00794-3

(65) Niu, W.;  Moehl, T.; Adams, P.; Zhang, X.; Lefèvre, R.; Cruz, A. M.; Zeng, P.; Kunze, K.; Yang, W.; Tilley, S. D.* Crystal orientation-dependent etching and trapping in thermally-oxidised Cu2O photocathodes for water splitting Energy & Environmental Science, 202215, 2002-2010.
doi: 10.1039/D1EE03696C

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(64) Yun, J.;  Tan, J.; Jung, Y.-K.; Yang, W.; Lee, H.; Ma, S.; Park, Y. S.; Lee, C. U.; Niu, W.; Lee, J.; Kim, K.; Tilley, S. D.; Walsh, A.*; Moon, J.* Interfacial Dipole Layer Enables High-Performance Heterojunctions for Photoelectrochemical Water Splitting ACS Energy Letters, 2022, 7, 1392-1402.
doi: 10.1021/acsenergylett.2c00392

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(63) Prabhakar, R. R.;  Moehl, T.; Friedrich, D.; Kunst, M.; Shukla, S.; Adeleye, A.; Damle, V. H.; Siol, S.; Cui, W.; Gouda, L.; Suh, J.; Tischler, Y. R.; van de Krol, R.; Tilley, S. D.* Sulfur-Treatment Passivates Bulk Defects in Sb2Se3 Photocathodes for Water Splitting Advanced Functional Materials, 2022.
doi: 10.1002/adfm.202112184

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(62) Bühler, J.;  Zurflüh, J.; Siol, S.; Blacque, O.; Sevéry, L.*; Tilley, S. D.* Electrochemical ruthenium-catalysed C–H activation in water through heterogenization of a molecular catalyst Catalysis Science & Technology, 2022, 12, 1512-1519.
doi: 10.1039/D1CY01999F

(61) Park, J.; Yoon, H.; Lee, D.-Y.; Ji, S. G.; Yang, W.; Tilley, S. D.; Sung, M.-C.; Park, I. J.; Tan, J.; Lee, H.; Kim, J. Y.; Kim, D.-W.; Moon, J.* Photovoltaic powered solar hydrogen production coupled with waste SO2 valorization enabled by MoP electrocatalysts Applied Catalysis B: Environmental, 2022305, 1–11.
doi: https://doi.org/10.1016/j.apcatb.2021.121045

(60) Nandy, S.; Wu, Q.; Tilley, S. D.*; Cui, C.* Improved water oxidation with metal oxide catalysts via a regenerable and redox-inactive ZnOxHy overlayer Chemical Communications, 2021, 79, 10230-10233.
doi: 10.1039/D1CC03406E

 

swarnava chem comm

 

(59) Gouda, L;  Sevéry, L.; Moehl, T.; Mas-Marzá, E.; Adams, P.; Fabregat-Santiago, F*; Tilley, S. D.* Tuning the selectivity of biomass oxidation over oxygen evolution on NiO–OH electrodes Green Chemistry, 2021, 23, 8061-8068.
doi: 10.1039/D1GC02031E

 

laxman toc

 

(58) Suh, J.; Tilley, S. D.* Tin Sulfide/Gallium Oxide Heterojunctions for Solar Water Splitting Energy Technology, 2021, 2100416.
doi: doi.org/10.1002/ente.202100461

 

Jihye toc

(57) Zhang, X.; Yang, W.*; Niu, W.; Adams, P.; Siol, S.; Wang, Z.; Tilley, S. D.* Thiol-Amine-Based Solution Processing of Cu2S Thin Films for Photoelectrochemical Water Splitting  ChemSusChem, 202114, 3967-3974.
doi: 10.1002/cssc.202101347

 

xi toc

 

(56) Yang, W.; Zhang, X.; Tilley, S. D.* Emerging Binary Chalcogenide Light Absorbers: Material Specific Promises and Challenges Chemistry of Materials, 2021, 33, 3467-3489. 
doi.org/10.1021/acs.chemmater.1c00741

chem mater review

(55) Sevéry, L.; Szczerbiński, J.; Taskin, M; Tuncay, I.; Nunes, F. B.; Cignarella, C.; Tocci, G.; Blacque, O.; Osterwalder, J.; Zenobi, R.; Lannuzzi, M.; Tilley, S. D.* Immobilization of molecular catalysts on electrode surfaces using host–guest interactions Nature Chemistry, 2021, 13, 523-529.
doi.org/10.1038/s41557-021-00652-y

(54) Oppelt, K. T.*; Sevéry, L.; Utters, Mirjam; Tilley, S. D.; and Hamm, P. Flexible to rigid: IR spectroscopic investigation of a rhenium-tricarbonyl-complex at a buried interface Phys. Chem. Chem. Phys., 2021, 23, 4311-4316
doi.org/10.1039/D0CP06546C

 

pccp paper

 

(53) Yang, W.; Moehl, T.; Service, E.; Tilley, S. D.* Operando Analysis of Semiconductor Junctions in Multi-Layered Photocathodes for Solar Water Splitting by Impedance Spectroscopy  Advanced Energy Materials, 2021, 11, 2003569
doi: 10.1002/aenm.202003569

(52) Yang, W.; Park, J.; Kwon, H.-C.; Hutter, O. S.; Phillips, L. J.; Tan, J.; Lee, H.; Lee, J.; Tilley, S. D.; Major, J. D.; Moon, J.* Solar water splitting exceeding 10 % efficiency via low-cost Sb2Se3 photocathodes coupled with semitransparent perovskite photovoltaics Energy & Environmental Science, 2020, 13, 4362-4370  
doi: https://doi.org/10.1039/D0EE02959A

(51) Prabhakar, R. R.; Moehl, T.; Siol, S.; Suh, J.; Tilley, S. D.*  Sb2S3/TiO2 Heterojunction Photocathodes: Band Alignment and Water Splitting Properties Chemistry of Materials, 2020, 32, 7247-7253
doi:10.1021/acs.chemmater.0c01581

(50) Weder, N.; Probst, B.; Sévery, L.; Fernández-Terán, R. J.; Beckord, J.; Blacque, O.; Tilley, S. D.; Hamm, P.; Osterwalder, J.; Alberto, R.*  Mechanistic insights into photocatalysis and over two days of stable H2 generation in electrocatalysis by a molecular cobalt catalyst immobilized on TiO2Catalysis Science & Technology, 2020, 10, 2549-2560
doi: https://doi.org/10.1039/D0CY00330A

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(49) Siol, S.*; Ott, N.; Beall, C.; Stiefel, M.; Untulmazsoy, Y.; Döbeli, M; Tilley, S. D.; Schmutz, P.; Jeurgens, L. P. H.; Cancellieri, C. A combinatorial guide to phase formation and surface passivation of tungsten titanium oxide prepared by thermal oxidation Acta Materialia, 2020, 186, 95-104.
doi: 10.1016/j.actamat.2019.12.026

(48) Cui, W.; Moehl, T.; Siol, S.; Tilley, S. D.* Operando electrochemical study of charge carrier processes in water splitting photoanodes protected by atomic layer deposited TiO2  Sustainable Energy Fuels 2019, 3, 3085 - 3092.
doi: 10.1039/C9SE00399A

(47) Yang, W.; Prabhakar, R. R.; Tan, J.; Tilley, S. D.;* Moon, J.* Strategies for Enhancing Photocurrent, Photovoltage, and Stability of Photoelectrodes for Photoelectrochemical Water Splitting Chem. Soc. Rev. 201948, 4979–5015.
doi: 10.1039/C8CS00997J

(46) Vijselaar, W; Kunturu, P. P.; Moehl, T.; Tilley, S. D.;* Huskens, J.* A Tandem Cuprous Oxide/Silicon Microwire Hydrogen-Evolving Photocathode with Photovoltage Exceeding 1.3 V ACS Energy Lett. 2019, 4, 2287–2294.
doi: 10.1021/acsenergylett.9b01402

(45) Moehl, T.; Cui, W.; Wick-Joliat, R.; Tilley, S. D.* Resistance-based analysis of limiting interfaces in multilayer water splitting photocathodes by impedance spectroscopy Sustainable Energy Fuels, 20193, 2067–2075.
doi: 10.1039/C9SE00248K

(44) Wick-Joliat, R.; Musso, T.; Prabhakar, R. R.; Loeckinger, J.; Siol, S.; Cui, W.; Sévery, L.; Moehl, T.; Suh, J.; Hutter, J.; Iannuzzi, M.; Tilley, S. D.* Stable and tunable phosphonic acid dipole layer for band edge engineering of photoelectrochemical and photovoltaic heterojunction devices Energy & Environmental Science, 201912, 1901–1909.
doi: 10.1039/C9EE00748B

(43) Tilley, S. D.*; Selloni, A.*; Hisatomi, T.* Preface to Special Issue of ChemSusChem—Water Splitting: From Theory to Practice ChemSusChem, 201912, 1771–1774.
doi: 10.1002/cssc.201900974

(42) Siol, S.; Beall, C.; Ott, N.; Döbeli, M.; González-Castaño, M; Wick-Joliat, R.; Tilley, S. D.; Jeurgens, L. P. H.; Schmutz, P; Cancellieri, C.  Anodizing of self-passivating WxTi1-x precursors for WxTi1-xOn oxide alloys with tailored stability ACS Appl. Mater. Interfaces, 201911, 9510–9518.
doi: 10.1021/acsami.8b19170

(41) Tilley, S. D.* Recent Advances and Emerging Trends in Photo‐Electrochemical Solar Energy Conversion Adv. Energy Mater., 2019, 9, 1802877. 
doi: 10.1002/aenm.201802877

(40) Sévery, L.; Siol, S.; Tilley, S. D.* Design of Molecular Water Oxidation Catalysts Stabilized by Ultrathin Inorganic Overlayers – Is Active Site Protection Necessary? Inorganics, 2018, 6, 105.
doi: 10.3390/inorganics6040105

(39) Cui, W.; Niu, W.; Wick-Joliat, R.; Moehl, T.; Tilley, S. D.* Operando Deconvolution of Photovoltaic and Electrocatalytic Performance in ALD TiO2 Protected Water Splitting Photocathodes Chem. Sci., 2018, 9, 6062-6067.
doi: 10.1039/C8SC01453A

(38) Prabhakar, R. R.; Cui, W.; Tilley, S. D.* New Earth-abundant Materials for Large-scale Solar Fuels Generation, Chimia, 2018, 72, 333–337.
doi: 10.2533/chimia.2018.333

(37) Kraack, J. P.; Sévery, L.; Tilley, S. D.; Hamm, P. Plasmonic Substrates Do Not Promote Vibrational Energy Transfer at Solid-Liquid Interfaces J. Phys. Chem. Lett., 2018, 9, 49–56.
doi: 10.1021/acs.jpclett.7b02855

(36) Niu, W.; Moehl, T.; Cui, W.; Wick, R.; Zhu, L.; Tilley, S. D.* Extended Light Harvesting with Dual Cu2O-based Photocathodes for High Efficiency Water Splitting Advanced Energy Materials, 2018, 8, 1702323.
doi: 10.1002/aenm.201702323

(35) Moehl, T.; Suh, J.; Sévery, L.; Wick-Joliat, R.;  Tilley, S. D.* Investigation of (Leaky) ALD TiO2 Protection Layers for Water Splitting Photoelectrodes ACS Appl. Mater. Interfaces, 2017, 9, 43614–43622.
doi: 10.1021/acsami.7b12564

(34) Prabhakar, R. R.; Septina, W.; Siol, S.; Moehl, T.; Wick-Joliat, R.; Tilley, S. D.* Photocorrosion-Resistant Sb2Se3 Photocathodes with Earth Abundant MoSx Hydrogen Evolution Catalyst J. Mater. Chem. A, 20175, 23139-23145.
doi: 10.1039/C7TA08993G

(33) Wang, F.; Septina, W.; Chemseddine, A.; Abdi, F. F.; Friedrich, D.; Bogdanoff, P.; van de Krol, R.; Tilley, S. D.; Berglund, S. P. Gradient self-doped CuBi2O4 with highly improved charge separation efficiency J. Am. Chem. Soc., 2017, 139, 15094–15103.
doi: 10.1021/jacs.7b07847

(32) Septina, W.; Tilley, S. D.* Emerging Earth-Abundant Materials for Scalable Solar Water Splitting  Curr. Opin. Electrochem., 2017, 2, 120-127.
doi: 10.1016/j.coelec.2017.03.010

(31) Pastor, E.; Le Formal, F.; Mayer, M. M.; Tilley, S. D.; Francàs, L.; Mesa, C. A.; Grätzel, M.; Durrant, J. R. Spectroelectrochemical analysis of the mechanism of (photo)electrochemical hydrogen evolution at a catalytic interface Nat. Commun., 2017, 8, 14280.
doi: 10.1038/ncomms14280

(30) Septina. W.; Prabhakar, R. R.; Wick, R.; Moehl, T.; Tilley, S. D.* Stabilized Solar Hydrogen Production with CuO/CdS Heterojunction Thin Film Photocathodes Chem. Mater. 2017, 29, 1735–1743.
doi: 10.1021/acs.chemmater.6b05248

(29) Siol, S.; Hellmann, J. C.; Tilley, S. D.; Grätzel, M.; Morasch, J.; Deuermeier, J.; Jaegermann, W.; Klein, A. Band Alignment Engineering at Cu2O/ZnO Heterointerfaces  ACS Appl. Mater. Interfaces, 20168, 21824–21831.
doi: 10.1021/acsami.6b07325

(28) Azevedo, J.; Tilley, S. D.; Schreier, M.; Stefik, M.; Sousa, C.; Araújo, J. P.; Mendes, A.; Grätzel, M.; Mayer, M. T. Tin Oxide as Stable Protective Layer for Composite Cuprous Oxide Water-Splitting Photocathodes. Nano Energy, 2016, 24, 10–16.
doi: 10.1016/j.nanoen.2016.03.022

(27) Wick, R.; Tilley, S. D.* Photovoltaic and Photoelectrochemical Solar Energy Conversion with Cu2O. J. Phys. Chem. C 2015, 119, 26243–26257.
doi: 10.1021/acs.jpcc.5b08397

(26) Dias, P.; Schreier, M.; Tilley, S. D.; Luo, J.; Azevedo, J.; Andrade, L.; Bi, D.; Hagfeldt, A.; Mendes, A.; Grätzel, M.; et al. Transparent Cuprous Oxide Photocathode Enabling a Stacked Tandem Cell for Unbiased Water Splitting. Adv. Energy Mater. 2015, 5, 1501537
doi: 10.1002/aenm.201501537

(25) Luo, J.; Li, Z.; Nishiwaki, S.; Schreier, M.; Mayer, M. T.; Cendula, P.; Lee, Y. H.; Fu, K. Cao, A.; Nazeeruddin, M. K.; Romanyuk, Y. E.; Buecheler, S.; Tilley, S. D.; Wong, L. H.; Tiwari, A. N.; Grätzel, M. Targeting Ideal Dual-Absorber Tandem Water Splitting Using Perovskite Photovoltaics and CuIn X Ga 1- X Se 2 Photocathodes. Adv. Energy Mater. 20155, 1501520.
doi: 10.1002/aenm.201501520

(24) Morales-Guio, C. G.; Mayer, M. T.; Yella, A.; Tilley, S. D.; Grätzel, M.; Hu, X. An Optically Transparent Iron Nickel Oxide Catalyst for Solar Water Splitting. J. Am. Chem. Soc. 2015, 137, 9927–9936.
doi: 10.1021/jacs.5b05544

(23) Le Formal, F.; Pastor, E.; Tilley, S. D.; Mesa, C. a; Pendlebury, S. R.; Grätzel, M.; Durrant, J. R. Rate Law Analysis of Water Oxidation on a Hematite Surface. J. Am. Chem. Soc. 2015, 137, 6629–6637.
doi: 10.1021/jacs.5b02576

(22) Luo, J.; Tilley, S. D.; Steier, L.; Schreier, M.; Mayer, M. T.; Fan, H. J.; Grätzel, M. Solution Transformation of Cu2O into CuInS2 for Solar Water Splitting. Nano Lett. 2015, 15, 1395–1402.
doi: 10.1021/nl504746b

(21) Schreier, M.; Gao, P.; Mayer, M. T.; Luo, J.; Moehl, T.; Nazeeruddin, M. K.; Tilley, S. D.; Grätzel, M. Efficient and Selective Carbon Dioxide Reduction on Low Cost Protected Cu2O Photocathodes Using a Molecular Catalyst. Energy Environ. Sci. 2015, 8, 855–861.
doi: 10.1039/C4EE03454F

(20) Morales-Guio, C. G.; Liardet, L.; Mayer, M. T.; Tilley, S. D.; Grätzel, M.; Hu, X. Photoelectrochemical Hydrogen Production in Alkaline Solutions Using Cu2O Coated with Earth-Abundant Hydrogen Evolution Catalysts. Angew. Chemie Int. Ed. 2015, 54, 664–667.
doi: 10.1002/anie.201410569

(19) Cendula, P.; Tilley, S. D.; Gimenez, S.; Bisquert, J.; Schmid, M.; Grätzel, M.; Schumacher, J. O. Calculation of the Energy Band Diagram of a Photoelectrochemical Water Splitting Cell. J. Phys. Chem. C 2014, 118, 29599–29607.
doi: 10.1021/jp509719d

(18) Luo, J.; Im, J.-H.; Mayer, M. T.; Schreier, M.; Nazeeruddin, M. K.; Park, N.-G.; Tilley, S. D.; Fan, H. J.; Gratzel, M. Water Photolysis at 12.3% efficiency via perovskite photovoltaics and Earth-abundant catalysis. Science 2014, 345, 1593.
doi: 10.1126/science.1258307

(17) Azevedo, J.; Steier, L.; Dias, P.; Stefik, M.; Sousa, C. T.; Araújo, J. P.; Mendes, A.; Graetzel, M.; Tilley, S. D.* On the Stability Enhancement of Cuprous Oxide Water Splitting Photocathodes by Low Temperature Steam Annealing. Energy Environ. Sci. 2014, 7, 4044–4052.
doi: 10.1039/C4EE02160F

(16) Steier, L.; Herraiz-Cardona, I.; Gimenez, S.; Fabregat-Santiago, F.; Bisquert, J.; Tilley, S. D.;* Grätzel, M. Understanding the Role of Underlayers and Overlayers in Thin Film Hematite Photoanodes. Adv. Funct. Mater. 2014, 24, 7681–7688.
doi: 10.1002/adfm.201402742

(15) Pendlebury, S. R.; Wang, X.; Formal, F. Le; Cornuz, M.; Kafizas, A.; Tilley, S. D.; Graetzel, M.; Durrant, J. R. Ultrafast Charge Carrier Recombination and Trapping in Hematite Photoanodes under Applied Bias. J. Am. Chem. Soc. 2014, 136, 9854.
doi: 10.1021/ja504473e

(14) Bornoz, P.; Abdi, F. F.; Tilley, S. D.; Dam, B.; van de Krol, R.; Grätzel, M.; Sivula, K. A Bismuth Vanadate–Cuprous Oxide Tandem Cell for Overall Solar Water Splitting. J. Phys. Chem. C 2014, 118, 16959.
doi: 10.1021/jp500441h

(13) Morales-Guio, C. G.; Tilley, S. D.; Vrubel, H.; Grätzel, M.; Hu, X. Hydrogen evolution from a copper(I) oxide photocathode coated with an amorphous molybdenum sulphide catalyst. Nat. Commun. 2014, 5, 3059.
doi: 10.1038/ncomms4059

(12) Tilley, S. David;* Schreier, M.; Azevedo, J.; Stefik, M.; Grätzel, M. Ruthenium Oxide Hydrogen Evolution Catalysis on Composite Cuprous Oxide Water Splitting PhotocathodesAdv. Func. Mat. 2014, 24, 303.
doi: 10.1002/adfm.201301106

(11) Le Formal, F.; Pendlebury, S. R.; Cornuz, M.; Tilley, S. David; Grätzel, M.; Durrant, J. R. Back electron-hole recombination in hematite photoanodes for water splitting. J. Am. Chem. Soc. 2014, 136, 2564.
doi: 10.1021/ja412058x

(10) Seger, B.; Tilley, S. David, Pedersen, T.; Vesborg, P.; Hansen, O.; Graetzel, M.; Chorkendorff, I. Silicon Protected with Atomic Layer Deposited TiO2: Conducting Versus Tunnelling Through TiO2. J. Mater. Chem. A. 2013, 1, 15089.
doi: 10.1039/c3ta12309j

(9) Seger, B.; Tilley, S. David, Pedersen, T.; Vesborg, P.; Hansen, O.; Graetzel, M.; Chorkendorff, I. Silicon Protected with Atomic Layer Deposited TiO2 – Durability Studies of Photocathodic H2 Evolution. RSC Adv. 2013, 3, 25902.
doi: 10.1039/c3ra45966g

(8) Reber, K.; Tilley, S. David; Carson, C.; Sorensen, E. Toward a synthesis of hirsutellone B by the concept of double cyclization. J. Org. Chem. 2013, 78, 9584-9607.
doi: 10.1021/jo401799f

(7) Rovelli, L.; Tilley, S. David; Sivula, K. Optimization and stabilization of electrodeposited p-type Cu2ZnSnS4 photocathodes for solar water reduction. ACS Appl. Mater. Interfaces 2013, 5, 8018-8024.
doi: 10.1021/am402096r

(6) Paracchino, A.; Matthews, N.; Hisatomi, T.; Stefik, M.; Tilley, S. David;* Grätzel, M. Ultrathin Films on Copper(I) Oxide Water Splitting Photocathodes: a Study on Performance and StabilityEnergy Environ. Sci. 2012, 5, 8673-8681.
doi: 10.1039/c2ee22063f

(5) Tilley, S. David; Cornuz, M.; Sivula, K., Grätzel, M. Light-Induced Water Splitting with Hematite: Improved Nanostructure and Iridium Oxide CatalysisAngew. Chem. Int. Ed. 2010, 49, 6405-6408. Featured in Nature, 2010, 466, 669.
doi: 10.1002/anie.201003110

(4) Reber, Keith P.; Tilley, S. David; Sorensen, Erik J. Bond formations by intermolecular and intramolecular trappings of acylketenes and their applications in natural product synthesis. Chem. Soc. Rev. 2009, 38, 3022-3034.
doi: 10.1039/b912599j

(3) Tilley, S. David; Reber, Keith P.; Sorensen, Erik J. A Rapid, Asymmetric Synthesis of the Decahydrofluorene Core of the Hirsutellones. Organic Letters. 2009, 11, 701-703.
doi: 10.1021/ol802768p

(2) Tilley, S. David; Joshi, N. S.; Francis, M. B. Proteins: Chemistry and Chemical Reactivity. In Wiley Encyclopedia of Chemical Biology; Tadhg P. Begley, Ed.; Wiley-VCH, 2009, 4, 158-174.
doi: 10.1002/9780470048672.wecb493

(1) Tilley, S. David; Francis, Matthew B. Tyrosine-Selective Protein Alkylation Using πAllylpalladium Complexes. J. Am. Chem. Soc. 2006, 128, 1080-1081.
doi: 10.1021/ja057106k